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The calculation uses equilibrium constants determined by statistical mechanics and a vibrational absorption spectrum determined by a coupled oscillator quantum mechanics model and ab initio quantum chemistry. 1Export Figures View in gallery Spectral distribution of the clear-sky Earth Radiation Budget components W m 2 cm 1 1 using a global-mean atmospherea Longwave irradiance emitted by surface B T sfc assuming it to be a blackbody the outgoing longwave radiation OLR clr and surface transmitted irradiance including the water vapor continuum STI clr cont.
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Based on the physico-chemical properties of water dimers their near infrared and visible absorption of solar radiation in the earths atmosphere is calculated.
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